… stability and eventual lone pair distortion of the hexahalide complexes and molecules of the fifth to eighth main-group elements with one lone pair, as isolated entities …

M Atanasov, D Reinen - Inorganic chemistry, 2005 - ACS Publications
… The latter polyhedron is unstable with respect to Sb III F 5 2 - and a single F - anion, …
transition-state theory. This two-parameter model 5 has been applied to lone pair species with CNs = …

Stabilization of unusual cationic species in protonic superacids and acidic melts

TA O'Donnell - Chemical Society Reviews, 1987 - pubs.rsc.org
… water molecules from one of more pairs of OH ligands to form VO… species which are unstable
in aqueous media increases. … metals in 'normal' oxidation states; but, more significantly from …

Particle motions in superionic conductors

A Rahman - The Journal of Chemical Physics, 1976 - pubs.aip.org
… ture solid state property of crt+ Fit namely, the flow of F-'s through a stable lattice of Ca2",s. …
show the three pair correlations gIJ(r) between the two kinds of particles. The cationcation pair

Superionic states formation in group III oxides irradiated with ultrafast lasers

RA Voronkov, N Medvedev, AE Volkov - Scientific Reports, 2022 - nature.com
state overlaps with plasma physics and chemistry, creating an unusual synergy—a warm
dense matter state (… of the materials into a superionic state under these conditions. Atomic and …

Transitions in superionic crystals

YY Gurevich, YI Kharkats - Journal of Physics and Chemistry of Solids, 1978 - Elsevier
… (x): the xz state conesponds to the maxi~m of Nxl and is consequently unstable. Variation of
T leads … the temperature interval between the pair of transitions widens and a pair of arbitrary …

Superionic conductivity and interionic potential

Y Kaneko, A Ueda, Y Hiwatari - Journal of the Physical Society of …, 1986 - journals.jps.jp
… The ionic soft-core system, as a model of oz-Agl, of which pair … , the anion sublattice is unstable
and has a tendency to deform … case IIIc for which the superionic state can not be realized. …

Thermodynamic aspects of superionic conductivity

YY Gurevich, YI Kharkats - Physics Reports, 1986 - Elsevier
… a special superionic state (electrolyte phase). It is in the latter … the total number of interacting
pairs is proportional to n2 and … ofFa ~ being thus unstable. Disordering without change in the …

Disorder in superionic fluorites

MJ Gillan, DD Richardson - Journal of Physics C: Solid State …, 1979 - iopscience.iop.org
state is still, for all practical purposes, unstable. We conclude that cube-centre interstitial-vacancy
pairs are essentially unstable at … will generally be unstable in the superionic state. This …

Coupled cation–anion dynamics enhances cation mobility in room-temperature superionic solid-state electrolytes

Z Zhang, PN Roy, H Li, M Avdeev… - Journal of the American …, 2019 - ACS Publications
… attention as essential materials for solid-state batteries, but a … Facile [PX 4 ] 3– anion rotation
exists in superionic Na 11 Sn … interplay where traditional transition state theory does not …

Features of the thermodynamics of superionic conductors

YY Gurevich, YI Kharkats - Soviet Physics Uspekhi, 1982 - iopscience.iop.org
… special state—the superionic state (electrolyte phase). In this … Now we consider that the total
number of interacting pairs … x2 corresponds to the maximum of F(x) and hence is unstable. …